Zinc-casting alloys
Casting alloys: Zinc-casting alloys can be grouped into two general categories: standard zinc die-casting alloys, and the newer ZA (zinc-aluminum) casting alloys.
Standard die-casting alloys: For pressure die casting, the established zinc alloys are the No. 3, 5, and 7 Zamak alloys. As die castings, they have good general-purpose tensile properties and can be cast in thin sections and with good dimensional accuracy. The alloys are often selected for plated or highly decorative applications because of their excellent finishing characteristics. Three major end-use areas for zinc die-cast components are automotive, building hardware, and electrical.
Zamak alloys contain approximately 4% aluminum with low percentages of magnesium, copper, and sometimes nickel. Impurities such as tin, lead, and cadmium are carefully controlled. These alloys are not recommended for gravity casting. They are cast by the hot-chamber die-casting process, which is different from, and more efficient than, the cold-chamber die-casting process commonly used for aluminum. In addition, a specialized process is used for efficient production of miniature die-cast components, using these alloys as well as ZA-8.
Typical tolerances of zinc die-cast parts are ±0.0015 in./in. for the first inch with an additional ±0.002 in./in. for larger parts. New zinc-casting technology allows for thin walls down to 0.025 in., improved internal soundness, and surface finishes that range typically from 32 to 64 rms.
Part dimensions change slightly when zinc die castings are aged. Zamak alloys No. 3 and 7 can shrink about 0.0007 in./in. after several weeks at room temperature. Alloy No. 5 responds similarly, but total shrinkage can be 0.0009 to 0.0024 in./in., followed by expansion of 0.0020 in./in. over a period of years. When it is necessary to bring these changes to completion within a short time after casting, a stabilizing treatment of 3 to 6 hr at 212°F is recommended.
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